Treatment of bimodality in proficiency test of pH in bioethanol matrix

The pH value in bioethanol is a quality control parameter related to its acidity and to the corrosiveness of vehicle engines when it is used as fuel. In order to verify the comparability and reliability of the measurement of pH in bioethanol matrix among some experienced chemical laboratories, reference material (RM) of bioethanol developed by Inmetro - the Brazilian National Metrology Institute - was used in a proficiency testing (PT) scheme. There was a difference of more than one unit in the value of the pH measured due to the type of internal filling electrolytic solutions (potassium chloride, KCl or lithium chloride, LiCl) from the commercial pH combination electrodes used by the participant laboratories. Therefore, bimodal distribution has occurred from the data of this PT scheme. This work aims to present the possibilities that a PT scheme provider can use to overcome the bimodality problem. Data from the PT of pH in bioethanol were treated by two different statistical approaches: kernel density model and the mixture of distributions. Application of these statistical treatments improved the initial diagnoses of PT provider, by solving bimodality problem and contributing for a better performance evaluation in measuring pH of bioethanol.Comment: 20 pages, 6 figures, Accepted for publication in Accreditation and Quality Assurance (ACQUAL

Hydration-induced anisotropic spin fluctuations in Na_{x}CoO_{2}\cdot1.3H_{2}O superconductor

We report ^{59}Co NMR studies in single crystals of cobalt oxide superconductor Na_{0.42}CoO_{2}\cdot1.3H_{2}O (T_c=4.25K) and its parent compound Na_{0.42}CoO_{2}. We find that both the magnitude and the temperature (T) dependence of the Knight shifts are identical in the two compounds above T_c. The spin-lattice relaxation rate (1/T_1) is also identical above T_0 \sim60 K for both compounds. Below T_0, the unhydrated sample is found to be a non-correlated metal that well conforms to Fermi liquid theory, while spin fluctuations develop in the superconductor. These results indicate that water intercalation does not change the density of states but its primary role is to bring about spin fluctuations. Our result shows that, in the hydrated superconducting compound, the in-plane spin fluctuation around finite wave vector is much stronger than that along the c-axis, which indicates that the spin correlation is quasi-two-dimensional.Comment: 4 pages, 5 figure

Effects from inhomogeneities in the chiral transition

We consider an approximation procedure to evaluate the finite-temperature one-loop fermionic density in the presence of a chiral background field which systematically incorporates effects from inhomogeneities in the chiral field through a derivative expansion. We apply the method to the case of a simple low-energy effective chiral model which is commonly used in the study of the chiral phase transition, the linear sigma-model coupled to quarks. The modifications in the effective potential and their consequences for the bubble nucleation process are discussed.Comment: 11 pages, 5 figures. v2: appendix and references added, published versio

ANALYSIS OF THE TURBULENCE-RADIATION INTERACTION IN A METHANE-AIR DIFFUSION FLAME

The phenomenon of turbulence-radiation interaction (TRI) has been demonstrated experimentally, theoretically and numerically to be important in a great number of engineering applications. This paper presents a numerical study on the subject, focusing on a methane-air diffusion flame confined in a rectangular enclosure. An open source, Fortran-based code, Fire Dynamics Simulator, is used for the analysis. Large Eddy Simulation (LES) is adopted to model the turbulence, and to resolve the sub-grid scale terms the dynamic Smagorinsky model is employed. To solve the radiative heat transfer, the finite volume method is used alongside the Weighted-Sum-of-Gray-Gases model. The main objective of the present work is to assess the magnitude of TRI effects for the configuration proposed. For this purpose, the time-averaged wall heat fluxes and volumetric radiative heat source, calculated from the LES results, are compared with those same quantities obtained by independent simulations initialized using mean temperature and species concentration fields. TRI effects are found to be responsible for differences up to 30% between results considering and neglecting turbulent fluctuations. These differences are larger for the radiative heat source and for the radiative heat flux to the walls, smaller for the total heat flux, and almost negligible for the convective heat flux. The influence of the fuel stream Reynolds number on the TRI effects is also evaluated, and a slight decrease on the magnitude of TRI is observed with the increase of that parameter

The Role of Fermions in Bubble Nucleation

We present a study of the role of fermions in the decay of metastable states of a scalar field via bubble nucleation. We analyze both one and three-dimensional systems by using a gradient expansion for the calculation of the fermionic determinant. The results of the one-dimensional case are compared to the exact results of previous work.Comment: 15 pages, revtex, 9 figure

Solvent-free process for the development of photocatalytic membranes

PTDC/EAM-AMB/30989/2017.This work described a new sustainable method for the fabrication of ceramic membranes with high photocatalytic activity, through a simple sol-gel route. The photocatalytic surfaces, prepared at low temperature and under solvent-free conditions, exhibited a narrow pore size distribution and homogeneity without cracks. These surfaces have shown a highly efficient and reproducible behavior for the degradation of methylene blue. Given their characterization results, the microfiltration photocatalytic membranes produced in this study using solvent-free conditions are expected to effectively retain microorganisms, such as bacteria and fungi that could then be inactivated by photocatalysis.publishe

Novel submerged photocatalytic membrane reactor for treatment of olive mill wastewaters

POCI-01-0145-FEDER-007265A new hybrid photocatalytic membrane reactor that can easily be scaled-up was designed, assembled and used to test photocatalytic membranes developed using the sol–gel technique. Extremely high removals of total suspended solids, chemical oxygen demand, total organic carbon, phenolic and volatile compounds were obtained when the hybrid photocatalytic membrane reactor was used to treat olive mill wastewaters. The submerged photocatalytic membrane reactor proposed and the modified membranes represent a step forward towards the development of new advanced treatment technology able to cope with several water and wastewater contaminants.publishersversionpublishe

Physical reflective boundary conditions applied to smoothed particle hydrodynamics (sph) method for solving fluid dynamics problems in 3-d domains

This paper aims to present the physical reflective boundary conditions (RBC) in 3-D domains and applications in fluid dynamics problems. Currently, RBC have been used in meshfree particle methods as an attempt to respect the continuum physical laws at the macroscopic domain, without the application of fictitious/ ghost particles - that improperly mix molecular and continuum mechanics concepts [1]. RBC methodology, validation in 2-D domains and applications in hydrostatics and hydrodynamics cases were presented in [2]. Hydrostatics and hydrodynamics cases with the RBC implementation in 3-D domains are presented in this work. A Newtonian, incompressible, uniform and isothermal fluid inside an immobile reservoir open to the atmosphere and dam break flow have been studied. In the first case, a modified SPH formulation using a modified pressure concept [3] has been used. Dam breaking simulations used the standard SPH formulation. In both cases, the numerical results showed good agreement with the analytical results or literature data

EXPERIMENTAL INVESTIGATION OF A PARAFFIN BASED HYBRID ROCKET

Hybrid rockets are known to be simpler, safer, environmentally friend, and, more importantly, cheaper than most of the technologies for propulsion devices used today. Hybrid rockets can be applied as the propulsion system in satellites launch vehicles, micro-satellites and tactical missiles. This paper deals with combustion of ultra-high molecular weight polyethylene (UHMWPE) and paraffin as the solid fuels burning with gaseous oxygen (GOX) as well as N O as the oxidizer in lab scale hybrid rocket motors. A test 2 stand was built to carry out the experiments. The main objectives were to investigate the ignition of the solid fuels, burning performance and regression rates for different operating conditions. With paraffin-based fuel the hybrid motor had the regression rate enhanced two to three folds compared to the UHMWPE, as reported in the literature. The overall performance of the motor, with paraffin as the fuel, is comparable to other technologies. Paraffin-based hybrid rockets can, then, be a safer and cheaper alternative to satellite launch vehicles for the Brazilian space program

Penetrating Bladder Trauma: A High Risk Factor for Associated Rectal Injury

Demographics and mechanisms were analyzed in prospectively maintained level one trauma center database 1990–2012. Among 2,693 trauma laparotomies, 113 (4.1%) presented bladder lesions; 51.3% with penetrating injuries (n=58); 41.3% (n=24) with rectal injuries, males corresponding to 95.8%, mean age 29.8 years; 79.1% with gunshot wounds and 20.9% with impalement; 91.6% arriving the emergence room awake (Glasgow 14-15), hemodynamically stable (average systolic blood pressure 119.5 mmHg); 95.8% with macroscopic hematuria; and 100% with penetrating stigmata. Physical exam was not sensitive for rectal injuries, showing only 25% positivity in patients. While 60% of intraperitoneal bladder injuries were surgically repaired, extraperitoneal ones were mainly repaired using Foley catheter alone (87.6%). Rectal injuries, intraperitoneal in 66.6% of the cases and AAST-OIS grade II in 45.8%, were treated with primary suture plus protective colostomy; 8.3% were sigmoid injuries, and 70.8% of all injuries had a minimum stool spillage. Mean injury severity score was 19; mean length of stay 10 days; 20% of complications with no death. Concomitant rectal injuries were not a determinant prognosis factor. Penetrating bladder injuries are highly associated with rectal injuries (41.3%). Heme-negative rectal examination should not preclude proctoscopy and eventually rectal surgical exploration (only 25% sensitivity)